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Crosslinked PVA/PVP Supported Silver Nanoparticles: A Reusable and Efficient Heterogeneous Catalyst for the 4-Nitrophenol Degradation

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Well-organized and stable silver nanoparticles (AgNPs) were successfully prepared within polymeric film of polyvinyl alcohol and Polyvinylpyrrolidone as supporting matrix. The free-standing film was obtained by using the casting technique.… Click to show full abstract

Well-organized and stable silver nanoparticles (AgNPs) were successfully prepared within polymeric film of polyvinyl alcohol and Polyvinylpyrrolidone as supporting matrix. The free-standing film was obtained by using the casting technique. Electron microscopy techniques confirmed the formation of spherical AgNPs of 15 nm size. The prepared AgNPs were crystallized in face-centered cubic structure as indicated by X-ray diffraction. The as-prepared nanocomposite film exhibited good catalytic properties in the complete catalytic degradation of 4-nitrophenol using sodium borohydride as a reducing agent. The AgNPs are tightly held within a polymeric matrix which facilitates their recovery and reuse for several cycles.

Keywords: supported silver; degradation; pvp supported; silver nanoparticles; pva pvp; crosslinked pva

Journal Title: Journal of Inorganic and Organometallic Polymers and Materials
Year Published: 2017

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