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Synthesis of Dialkenyl-Substituted Double-Decker Silsesquioxanes as Precursors for Linear Copolymeric Systems

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In this paper, we report an efficient synthetic route for dialkenyl-substituted double-decker silsesquioxane derivatives as difunctional reagents for further applications. This study concerns synthesis of allyl, hex-5-enyl- and dec-9-enyl-double-decker silsesquioxanes… Click to show full abstract

In this paper, we report an efficient synthetic route for dialkenyl-substituted double-decker silsesquioxane derivatives as difunctional reagents for further applications. This study concerns synthesis of allyl, hex-5-enyl- and dec-9-enyl-double-decker silsesquioxanes obtained via condensation and hydrosilylation process as alternative processes, with high yields. The presence of unsaturated groups allows these compounds to be used as molecular synthons for hybrid silsesquioxane based systems of macromolecular nature.Graphical Abstract

Keywords: substituted double; decker silsesquioxanes; dialkenyl substituted; double decker; decker

Journal Title: Journal of Inorganic and Organometallic Polymers and Materials
Year Published: 2017

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