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Temperature dependence of dynamic mechanical behaviors in low density MTMS-derived silica aerogel

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In this work, methyltrimethoxysilane (MTMS) derived silica aerogel with the low density of about 38 mg/cm3 was prepared via ethanol supercritical fluid drying. Nondestructive dynamic mechanical analyzer (DMA) was successfully used… Click to show full abstract

In this work, methyltrimethoxysilane (MTMS) derived silica aerogel with the low density of about 38 mg/cm3 was prepared via ethanol supercritical fluid drying. Nondestructive dynamic mechanical analyzer (DMA) was successfully used to characterize its mechanical behavior in the temperature range − 150–300 °C. The DMA results reveal that the storage modulus of low density aerogel is under 0.25 MPa and keep almost constant over a broad temperature range − 150–300 °C, while the storage modulus of high density aerogel (247 mg/cm3) is beyond 2.5 MPa and change noticeably in the same temperature range. The MTMS-derived low density silica aerogel have not only excellent stable mechanical property, but also low thermal conductivity (0.02591 W/mK) and super-hydrophobicity (contact angle 160°), which results in the potential application for the space exploration.

Keywords: derived silica; temperature; silica aerogel; density; low density; mtms derived

Journal Title: Journal of Porous Materials
Year Published: 2017

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