Rutile TiO2 single crystals (SCs) were implanted with Cu ions. The implantation effect on microstructure and magnetic behavior of Cu-doped TiO2 wafers was investigated. The implanted ions are in part… Click to show full abstract
Rutile TiO2 single crystals (SCs) were implanted with Cu ions. The implantation effect on microstructure and magnetic behavior of Cu-doped TiO2 wafers was investigated. The implanted ions are in part successfully incorporated in the host lattice gradually forming a CuO-like species. Although the projected range is ∼117 nm, the induced defects extend much deeper. Room temperature ferromagnetism (RTFM) was observed both in undoped and Cu-doped TiO2 SCs. Their saturation magnetizations were found to be nearly equal to each other, in agreement with our theoretical calculations. Additionally, no superparamagnetism was examined in the zero-field cooled (ZFC) versus field cooled (FC) measurements, revealing an intrinsic ferromagnetic nature in each SC.
               
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