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The partial molar volumes and isentropic compressions of aqueous solutions of tetrahydrofuran, tetrahydropyran, 1,4-dioxane, tetrahydropyran-2-methanol, 3-hydroxytetrahydrofuran, and tetrahydrofurfuryl alcohol were measured at 288.15, 298.15, and 313.15 K. Results are analyzed in… Click to show full abstract
The partial molar volumes and isentropic compressions of aqueous solutions of tetrahydrofuran, tetrahydropyran, 1,4-dioxane, tetrahydropyran-2-methanol, 3-hydroxytetrahydrofuran, and tetrahydrofurfuryl alcohol were measured at 288.15, 298.15, and 313.15 K. Results are analyzed in terms of the effects of group addition to the molar volumes and isentropic compressions. The temperature dependence of the molar volumes and compressions, and their group contributions, are used to characterize changes in hydration.
Journal Title: Journal of Solution Chemistry
Year Published: 2018
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