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Questions are raised regarding whether or not the curve-fit equation coefficients reported by He and cowokers for the Kamlet and Taft linear solvent energy relationship model are meaningful. One of… Click to show full abstract
Questions are raised regarding whether or not the curve-fit equation coefficients reported by He and cowokers for the Kamlet and Taft linear solvent energy relationship model are meaningful. One of the calculated coefficients suggests that the solubility of 2-nitro-3-methylbenzoic acid decreases with increasing hydrogen-bond acidity of the solvent. The Abraham general solvation parameter model is suggested as a better model for obtaining information regarding molecular interactions between 2-nitro-3-methylbenzoic acid and surrounding solvent molecules.
Journal Title: Journal of Solution Chemistry
Year Published: 2019
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