LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

The Volumetric Properties of Ternary Solutions of Glycine + H2O + LiBr, NaBr or KBr at T = (293.15–313.15) K and Ambient Pressure

Photo from wikipedia

In this study, densities of binary and ternary solutions containing (glycine + water), (glycine + water + lithium bromide), (glycine + water + potassium bromide) and (glycine + water + sodium bromide) have been measured using a vibrating U-tube densimeter at T = (293.15 to 313.15)… Click to show full abstract

In this study, densities of binary and ternary solutions containing (glycine + water), (glycine + water + lithium bromide), (glycine + water + potassium bromide) and (glycine + water + sodium bromide) have been measured using a vibrating U-tube densimeter at T = (293.15 to 313.15) K. The apparent molar volumes have been calculated from the obtained density data. Apparent molar volumes at infinite dilution, $$ V_{\phi }^{0} $$Vϕ0, were fitted to a Redlich–Meyer type equation. The limiting apparent molar expansibility, $$ E_{\phi }^{0} $$Eϕ0, was calculated from the first derivative of the limiting apparent molar volumes with respect to temperature. By analyzing the obtained volumetric data, the hydration numbers for glycine, nH, were also calculated in these solutions. The results indicate that the apparent molar volumes increase with temperature. Moreover, it has been proven that glycine acts as a structure maker in the studied solutions.

Keywords: 293 313; molar volumes; glycine water; ternary solutions; apparent molar

Journal Title: Journal of Solution Chemistry
Year Published: 2019

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.