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Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate

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Di-1-methyl heptyl methyl phosphonate (DMHMP) is a promising alternative extractant for Th-U fuel reprocessing, in which the irradiation stability of extractant should be systematically studied. In this paper, the radiolysis… Click to show full abstract

Di-1-methyl heptyl methyl phosphonate (DMHMP) is a promising alternative extractant for Th-U fuel reprocessing, in which the irradiation stability of extractant should be systematically studied. In this paper, the radiolysis products of DMHMP were analyzed qualitatively and quantitatively with gas and ion chromatograph, the possible radiolysis mechanism of DMHMP was also concluded. Moreover, the effect of structure on the radiolysis products and irradiation stability of neutral organophosphorus compound extractant was also discussed.

Keywords: radiolysis products; heptyl methyl; radiolysis; methyl heptyl; methyl phosphonate

Journal Title: Journal of Radioanalytical and Nuclear Chemistry
Year Published: 2017

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