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Highly efficient removal of uranium(VI) from aqueous solutions by poly(acrylic acid-co-acrylamide) hydrogels

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In this study, poly(acrylic acid-co-acrylamide) (PAAAM) hydrogels were used to remove uranium (VI) ions in wastewater and characterized by FTIR, SEM, EDX. The effects of pH value, coexistence of ionic… Click to show full abstract

In this study, poly(acrylic acid-co-acrylamide) (PAAAM) hydrogels were used to remove uranium (VI) ions in wastewater and characterized by FTIR, SEM, EDX. The effects of pH value, coexistence of ionic strength, contact time, initial U (VI) ion concentration and adsorption temperature were also studied. Adsorption data fitted well with pseudo-second-order, intra-particle diffusion model and Langmuir isotherm mode, the maximum adsorption capacity of U(VI) was 713.24 mg g−1. Thermodynamic analysis shows that the adsorption of U(VI) is spontaneous endothermic. PAAAM hydrogel has excellent regeneration performance, after five time adsorption–desorption cycles, the adsorbent still maintained 99.24% adsorption capacity.

Keywords: adsorption; poly acrylic; acrylic acid; efficient removal; acid acrylamide; highly efficient

Journal Title: Journal of Radioanalytical and Nuclear Chemistry
Year Published: 2018

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