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Thin layer chromatography for astatine and iodine in solutions prepared by dry distillation

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The astatine radionuclides 208,209,210,211At and the iodine radionuclides 120,121,123I were simultaneously produced by 7Li beam irradiation of a stack of lead and tin targets. The astatine and the iodine radionuclides… Click to show full abstract

The astatine radionuclides 208,209,210,211At and the iodine radionuclides 120,121,123I were simultaneously produced by 7Li beam irradiation of a stack of lead and tin targets. The astatine and the iodine radionuclides each were separated from the irradiated target with a dry distillation method. No-carrier-added astatine and iodine solutions were prepared using ethanol or water as a solvent. Astatine in the aqueous solution was reacted with an oxidizing or a reducing agent. Separation of the astatine and the iodine ions in the solutions was conducted by thin layer chromatography on silica gel with an ethanol/water solution. Astatine was separated and identified as anions of Atβˆ’, AtO3βˆ’ and AtO4βˆ’, while iodine was Iβˆ’, compared with the standard iodine species.

Keywords: solutions prepared; layer chromatography; dry distillation; astatine iodine; thin layer; iodine solutions

Journal Title: Journal of Radioanalytical and Nuclear Chemistry
Year Published: 2018

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