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Catalytic performance of KL zeolite-supported iron and cobalt catalysts for the Fischer–Tropsch synthesis

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In this work, Fe and Co were introduced into a KL zeolite support by incipient wetness impregnation to obtain catalysts for the Fischer–Tropsch synthesis (FTS). The samples were analyzed by… Click to show full abstract

In this work, Fe and Co were introduced into a KL zeolite support by incipient wetness impregnation to obtain catalysts for the Fischer–Tropsch synthesis (FTS). The samples were analyzed by several techniques including atomic absorption spectroscopy (AAS), N2 adsorption, X-ray diffraction (XRD), H2-temperature programmed reduction (TPR) and transmission electron microscopy (TEM). The catalytic performance for the FTS was tested with a fixed bed reactor. The particle size distribution of the samples was estimated by TEM microphotographs and showed that the diameters of the iron and cobalt particles were ~ 6 nm and 8–20 nm, respectively. The catalyst with the higher percentage of iron promoted the highest CO conversion, and the distribution of the products was shifted to light fractions. The iron-based catalysts were more active than cobalt in the CO conversion, but the latter yielded a higher content of hydrocarbons with 5 and more carbons.

Keywords: cobalt; catalysts fischer; tropsch synthesis; fischer tropsch; catalytic performance; iron cobalt

Journal Title: Reaction Kinetics, Mechanisms and Catalysis
Year Published: 2018

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