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Electrode material containing carbon nanotubes and its kinetic characteristics of oxygen electroreduction

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In this article, we report on the study of the electrochemical characteristics of the electrode material of a proton exchange membrane (PEM) fuel cell containing carbon nanotubes (CNTs) as a… Click to show full abstract

In this article, we report on the study of the electrochemical characteristics of the electrode material of a proton exchange membrane (PEM) fuel cell containing carbon nanotubes (CNTs) as a functional additive in the oxygen reduction reaction. The data of appraisal by the methods of scanning and transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), differential thermal analysis, cyclic and direct voltammetry on a stationary and rotating disk electrode are given. The results showed that the material has a higher electrode activity in the presence of oxygen-modified carbon nanotubes, a higher half-wave potential of oxygen electroreduction (610 and 500 mV in the presence and absence of CNTs, respectively), showed a threefold higher density of the kinetic current of oxygen reduction, has a 2.5-fold higher density of exchange current in the oxygen reaction. This can be explained by the effect of oxygen-modified CNTs on the content of surface oxide (PtO); in the presence of CNTs, the PtO content is lower.

Keywords: oxygen; containing carbon; carbon nanotubes; electrode material; oxygen electroreduction

Journal Title: Reaction Kinetics, Mechanisms and Catalysis
Year Published: 2020

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