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Carane-derived β-amino alcohols with amino and hydroxy groups at positions 3 and 4 differing in their mutual arrangement and configuration were synthesized. Their application as organocatalysts in the asymmetric aldol… Click to show full abstract
Carane-derived β-amino alcohols with amino and hydroxy groups at positions 3 and 4 differing in their mutual arrangement and configuration were synthesized. Their application as organocatalysts in the asymmetric aldol reaction of isatin with acetone allowed one to obtain adducts with up to 84% enantiomeric excess.
Keywords:
isatin acetone;
aldol reaction;
organocatalysts asymmetric;
amino alcohols;
asymmetric aldol;
reaction isatin
Journal Title: Russian Chemical Bulletin
Year Published: 2017
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Journal Title: Russian Chemical Bulletin
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!