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Nitrosation of 2-(1-adamantylmethyl)-1,1-dichlorocyclopropane with either adduct NOCl•(SO3)n or nitrosonium tetrafluoroborate gives 3- and 4-(1-adamantylmethyl)-5-chloroisoxazoles in good yields. The presence of a linker between cyclopropane ring and adamantane moiety is essential… Click to show full abstract
Nitrosation of 2-(1-adamantylmethyl)-1,1-dichlorocyclopropane with either adduct NOCl•(SO3)n or nitrosonium tetrafluoroborate gives 3- and 4-(1-adamantylmethyl)-5-chloroisoxazoles in good yields. The presence of a linker between cyclopropane ring and adamantane moiety is essential for enabling nitrosation—heterocyclization of adamantyl 1,1-dichlorocyclopropanes.
Keywords:
dichlorocyclopropanes new;
adamantyl;
approach adamantyl;
new approach;
nitrosation adamantyl;
adamantyl dichlorocyclopropanes
Journal Title: Russian Chemical Bulletin
Year Published: 2017
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Journal Title: Russian Chemical Bulletin
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!