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Thermal decomposition of ammonium perchlorate in the presence of bimetallic additives

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The catalytic activity of the thermolysis products of double complex compounds in the decomposition reaction of ammonium perchlorate was studied. The products used are C1.4N1.6H3CoFe (I), C6N8Co4Fe3 (II), O11Co4Fe3 (III),… Click to show full abstract

The catalytic activity of the thermolysis products of double complex compounds in the decomposition reaction of ammonium perchlorate was studied. The products used are C1.4N1.6H3CoFe (I), C6N8Co4Fe3 (II), O11Co4Fe3 (III), O8.5(CN)0.3Cu3Fe2 (IV), and reactive CuO. All active phases decrease the temperature of complete decomposition of NH4ClO4, and the order of temperature decreasing is the following: I ≈ II (120 °C) > IV > III (80 °C) ≫ CuO.

Keywords: decomposition ammonium; thermal decomposition; ammonium perchlorate; decomposition

Journal Title: Russian Chemical Bulletin
Year Published: 2018

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