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Synthesis of water-soluble bis-N,O-chelate nickel(II) complexes based on new ligands – P-pyridyl-containing phospholane oxides

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A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL2(H2O)2](BF4)2 and [NiL2(MeCN)2](BF4)2. Physicochemical… Click to show full abstract

A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL2(H2O)2](BF4)2 and [NiL2(MeCN)2](BF4)2. Physicochemical properties and crystalline structures of the synthesized compounds were thoroughly studied.

Keywords: nickel complexes; soluble bis; synthesis water; water soluble

Journal Title: Russian Chemical Bulletin
Year Published: 2018

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