A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL2(H2O)2](BF4)2 and [NiL2(MeCN)2](BF4)2. Physicochemical… Click to show full abstract
A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL2(H2O)2](BF4)2 and [NiL2(MeCN)2](BF4)2. Physicochemical properties and crystalline structures of the synthesized compounds were thoroughly studied.
               
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