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Influence of aging of poly[(trimethylsilyl)prop-1-yne] on the thermodynamics of sorption of light hydrocarbons

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Changes in the properties of the poly[(trimethylsilyl)prop-1-yne] (PTMSP) film deposited on the walls of a quartz capillary under the action of high temperatures were studied by chromatographic methods. The change… Click to show full abstract

Changes in the properties of the poly[(trimethylsilyl)prop-1-yne] (PTMSP) film deposited on the walls of a quartz capillary under the action of high temperatures were studied by chromatographic methods. The change in the thermodynamic parameters of sorption of light hydrocarbons related to both physical aging of the PTMSP film and, possibly, its chemical destruction was examined.

Keywords: thermodynamics; sorption light; trimethylsilyl prop; light hydrocarbons; prop yne; poly trimethylsilyl

Journal Title: Russian Chemical Bulletin
Year Published: 2018

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