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New 2-(2-pyridyl)-substituted benzothiazoles with polyethylene glycol substituents

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An approach for the synthesis of new organic ligands combining in their structure pyridine, benzothiazole, and polyethylene glycol fragments was developed, proceeding from 6-hydroxy-2-(pyridin-2-yl)benzothiazole and mono- or ditosyl-substituted polyethylene glycols.… Click to show full abstract

An approach for the synthesis of new organic ligands combining in their structure pyridine, benzothiazole, and polyethylene glycol fragments was developed, proceeding from 6-hydroxy-2-(pyridin-2-yl)benzothiazole and mono- or ditosyl-substituted polyethylene glycols. The ligand 2-(2-{[2-(pyridin-2-yl)benzothiazol-6-yl]oxy}ethoxy)ethanol (L) in the reaction with Cu(ClO4)2•6 H2O and CuCl2•2 H2O formed coordination compounds of the composition L2Cu(ClO4)2•7 H2O and LCuCl2•0.5 H2O, respectively.

Keywords: substituted benzothiazoles; h2o; new pyridyl; pyridyl substituted; polyethylene glycol; benzothiazoles polyethylene

Journal Title: Russian Chemical Bulletin
Year Published: 2019

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