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Synthesis and some properties of the salts of N-(het)aryl-N´-hydroxydiazene N-oxides

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Salts of N-(het)aryl-N´-hydroxydiazene N-oxides were synthesized by the reaction of sodium nitrohydroxylaminate (Angeli´s salt) with the appropriate nitro compounds. The ion exchange reactions gave the corresponding copper and lead salts.… Click to show full abstract

Salts of N-(het)aryl-N´-hydroxydiazene N-oxides were synthesized by the reaction of sodium nitrohydroxylaminate (Angeli´s salt) with the appropriate nitro compounds. The ion exchange reactions gave the corresponding copper and lead salts. The thermal stability of the synthesized salts was evaluated. Methylation of the synthesized salts afforded N-(het)aryl-N´-methoxydiazene N-oxides.

Keywords: aryl hydroxydiazene; synthesis properties; hydroxydiazene oxides; het aryl; salts het

Journal Title: Russian Chemical Bulletin
Year Published: 2020

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