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New transformations of phosphorylthioformic acid morpholides

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Phosphorylthioformic acid morpholides can be successfully used as a precursor in the synthesis of complexes of phosphoryl-substituted thiohydrazides with hydrazine and morpholine. The reaction of sterically hindered phosphorylthioformic acid morpholides… Click to show full abstract

Phosphorylthioformic acid morpholides can be successfully used as a precursor in the synthesis of complexes of phosphoryl-substituted thiohydrazides with hydrazine and morpholine. The reaction of sterically hindered phosphorylthioformic acid morpholides with hydrazine hydrate proceeds chemoselectively with the formation of hydrazono(morpholino)methylphosphodiamides.

Keywords: phosphorylthioformic acid; acid morpholides; new transformations; transformations phosphorylthioformic

Journal Title: Russian Chemical Bulletin
Year Published: 2020

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