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The fast absorption of molecular oxygen by a system including styrene oxide, copper(II) chloride, and α-naphthol (strong inhibitor of oxidation) was found and studied by the volumetric method. A low… Click to show full abstract
The fast absorption of molecular oxygen by a system including styrene oxide, copper(II) chloride, and α-naphthol (strong inhibitor of oxidation) was found and studied by the volumetric method. A low value of the activation energy of oxidation and a complicated concentration dependence of the reaction rate indicate that the oxidation proceeds via the formation of a ternary system, possibly, via a complex of three reactants. The thermolabile activity of the copper catalyst of oxidation was found for the oxidation of this system in a 85 vol.% ButOH + + 15 vol.% H2O solution.
Journal Title: Russian Chemical Bulletin
Year Published: 2020
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