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A Pd-catalyzed difunctionalization of internal alkynes combining boronic acids and perfluoroalkyl iodides under mild conditions is described here. Tetrasubstituted olefins containing perfluoroalkyl groups are synthesized in high yields in a… Click to show full abstract
A Pd-catalyzed difunctionalization of internal alkynes combining boronic acids and perfluoroalkyl iodides under mild conditions is described here. Tetrasubstituted olefins containing perfluoroalkyl groups are synthesized in high yields in a regio- and stereoselective manner. Mechanistic studies have been carried out to shed light on the nature of the likely intermediates involved in these transformations.
Keywords:
alkynes mechanistic;
internal alkynes;
carboperfluoroalkylation internal;
stereoselective carboperfluoroalkylation;
mechanistic insights
Journal Title: Topics in Catalysis
Year Published: 2017
Link to full text (if available)
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Journal Title: Topics in Catalysis
Year Published: 2017
Link to full text (if available)
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recommendations!