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Vermicompost as a natural adsorbent: evaluation of simultaneous metals (Pb, Cd) and tetracycline adsorption by sewage sludge-derived vermicompost

The simultaneous adsorption of heavy metals (Pb, Cd) and organic pollutant (tetracycline (TC)) by a sewage sludge-derived vermicompost was investigated. The maximal adsorption capacity for Pb, Cd, and TC in… Click to show full abstract

The simultaneous adsorption of heavy metals (Pb, Cd) and organic pollutant (tetracycline (TC)) by a sewage sludge-derived vermicompost was investigated. The maximal adsorption capacity for Pb, Cd, and TC in a single adsorptive system calculated from Langmuir equation was 12.80, 85.20, and 42.94 mg L−1, while for mixed substances, the adsorption amount was 2.99, 13.46, and 20.89 mg L−1, respectively. The adsorption kinetics fitted well to the pseudo-second-order model, implying chemical interaction between adsorbates and functional groups, such as –COOH, –OH, –NH, and –CO, as well as the formation of organo-metal complexes. Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET) specific surface area measurement were adopted to gain insight into the structural changes and a better understanding of the adsorption mechanism. The sewage sludge-derived vermicompost can be a low cost and environmental benign eco-material for high efficient wastewater remediation.

Keywords: derived vermicompost; adsorption; sewage sludge; sludge derived

Journal Title: Environmental Science and Pollution Research
Year Published: 2017

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