LAUSR

The combined effects and respective advantages of using pyrite and alkali-modified rice husk (RH) were studied as substrates for nitrogen and phosphorus removal from constructed wetlands, and the effects of the carbon to nitrogen (C/N) ratio and the tidal flow mode on system performance were explored. The results showed that alkali-modified RH, which enhances heterotrophic denitrification, had far more advantages than pyrite, which enhances autotrophic denitrification, and alkali-modified RH can be used for the treatment of sewage containing low C/N ratios. At a C/N ratio of 1.5, the total nitrogen (TN) removal rates exceeded 95%. However, the removal efficiency of the system with only pyrite only reached 76.90% when the influent C/N ratio was 6. Pyrite achieved a total phosphorus (TP) removal 10–20% higher than that of the control group. The tidal flow CWs showed enhanced nitrification, and the NH4+-N removal rates increased by approximately 10%, but the increase in dissolved oxygen (DO) was still insufficient to meet the needs of the systems, leading to limited TP removal. The combination of pyrite and alkali-modified RH was optimal for improving the ability of constructed wetlands to treat wastewaters, simultaneously removing nitrogen and phosphorus from sewage containing low C/N ratios. Combined with the tidal flow mode strategy, the use of pyrite and alkali-modified RH as substrates showed substantial advantages for improving water quality.