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Cyclic voltammetry and square wave voltammetry were used to investigate reduction mechanism of Ti(IV) on the iron electrode surface in NaCl-KCl-NaF molten salt system. It indicated that the Ti(IV) ions… Click to show full abstract
Cyclic voltammetry and square wave voltammetry were used to investigate reduction mechanism of Ti(IV) on the iron electrode surface in NaCl-KCl-NaF molten salt system. It indicated that the Ti(IV) ions were reduced to titanium metal by three steps, Ti(IV) → Ti(III) → Ti(II) → Ti, and the reduction process was irreversible process controlled by diffusion. The nucleation mechanism of titanium ions on pure iron electrode surface was determined to be an instantaneous nucleation process.
Keywords:
nacl kcl;
salt system;
molten salt;
kcl naf;
naf molten
Journal Title: Ionics
Year Published: 2018
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Journal Title: Ionics
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!