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Synthesis and investigation of quinazoline derivatives based on 8-hydroxyquinoline as corrosion inhibitors for mild steel in acidic environment: experimental and theoretical studies

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HCl pickling treatment is utilized to remove mill scales from mild steel (MS) surface at different temperatures up to 328 ± 2 K. In order to minimize the metal dissolution, newly multifunctional heterocycles… Click to show full abstract

HCl pickling treatment is utilized to remove mill scales from mild steel (MS) surface at different temperatures up to 328 ± 2 K. In order to minimize the metal dissolution, newly multifunctional heterocycles based on 8-hydroxyquinoline namely 3-((8-hydroxyquinolin-5yl)-methyl)-2-phenylquinazolin-4(3H)-one (HQ-ZH), 3-((8-hydroxyquinliene-5-yl)-2-(4-nitrophenyl)-quinazolin-4(3H)-one (HQ-ZNO2), and 2-(2-hydroxyphenyl)-3-((8-hydroxyquinolin-5-yl)-methyl)-quinazolin-4(3H)-one (HQ-ZOH) have been synthesized and characterized by Fourier transform infrared (FT-IR), 1H,13C NMR, and elemental analysis. Their anticorrosive performance for the mild steel in 1 M HCl medium has been determined by electrochemical and theoretical investigations. HQ-ZH, HQ-ZOH, and HQ-ZNO2 act as excellent inhibitors for MS in 1 M HCl. In addition, the surface of the mild steel has been analyzed by the UV-visible and SEM. The experimental results were correlated with theoretical studies.

Keywords: mild steel; theoretical studies; synthesis investigation; steel; based hydroxyquinoline; investigation quinazoline

Journal Title: Ionics
Year Published: 2018

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