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Electrochemical Measurements of a Conducting Polymer for Optimizing Detector Applications

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An electrochemical method was used to prepare polyaniline (PANI) with hydrochloric acid as a dopant. This electroactive material was fabricated using electrically modified carbon coated Teflon electrodes with an area… Click to show full abstract

An electrochemical method was used to prepare polyaniline (PANI) with hydrochloric acid as a dopant. This electroactive material was fabricated using electrically modified carbon coated Teflon electrodes with an area of 0.64 cm2 in 1 M HCl. PANI was electrochemically synthesized using cyclic voltammetry (CV) with a variable number of cycles, scan rates, and step sizes at potentials ranging from − 0.2 V to 0.8 V. Fabricated samples were tested using different electrochemical techniques including CV, differential pulse voltammetry (DPV) and electrochemical impedance spectroscopy (EIS). The DPV and EIS measurements indicate a linear relationship between both the current peak and the charge transfer resistance (Rct) and pH. These measurements showed that the prepared electrochemical device can be used as a sensor for pH. Optimum preparation parameters were 30 cycles, 50 mV/s scan rate and 2 mV step size. A linear relationship between oxidation current and pH of the solution with a correlation coefficient of 0.97 in the range of 1–5 makes PANI a candidate to be used as a pH sensor.

Keywords: optimizing detector; measurements conducting; detector applications; conducting polymer; polymer optimizing; electrochemical measurements

Journal Title: Journal of Electronic Materials
Year Published: 2018

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