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Electrochemical Performance of Green Stabilizer- and Biomolecule-Assisted PbWO4 Nanoparticles

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Lead tungstate (PbWO4) nanoparticles were synthesized using plant extracts [Ocimum tenuiflorum (thulasi) and Mentha (mint)] and biomolecules (l-arginine and l-histidine) by a precipitation method. The synthesized PbWO4 particles were characterized… Click to show full abstract

Lead tungstate (PbWO4) nanoparticles were synthesized using plant extracts [Ocimum tenuiflorum (thulasi) and Mentha (mint)] and biomolecules (l-arginine and l-histidine) by a precipitation method. The synthesized PbWO4 particles were characterized using x-ray diffraction (XRD), Fourier transform infrared spectroscopy, scanning electron microscopy (SEM), energy-dispersive x-ray (EDX) analysis, transmission electron microscopy (TEM), UV–visible (UV–Vis) spectrophotometry, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The XRD patterns confirm a pure-phase tetragonal structure for all the synthesized samples, with crystallite size ranging from 31 nm to 73 nm. From SEM and TEM images, morphological changes are observed, due mainly to the influence of adding biomolecules and plant leaf extracts. CV and EIS analysis indicate that PbWO4 nanoparticles are a better material for supercapacitor applications.

Keywords: pbwo4 nanoparticles; microscopy; performance green; spectroscopy; green stabilizer; electrochemical performance

Journal Title: Journal of Electronic Materials
Year Published: 2020

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