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Ethanol Biofuel Cell Utilizing Photo-Excited Flavin-Mediated Oxidation of β-Nicotinamide Adenine Dinucleotide Hydrate (NADH) at the Anode and Reduction of H+ Ions at the Cathode

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At the anode, the electrochemical oxidation of β-nicotinamide adenine dinucleotide hydrate (NADH) to its oxidized form (NAD+) spontaneously proceeded using photo-excited flavin mononucleotide (FMN) as the redox mediator. At the… Click to show full abstract

At the anode, the electrochemical oxidation of β-nicotinamide adenine dinucleotide hydrate (NADH) to its oxidized form (NAD+) spontaneously proceeded using photo-excited flavin mononucleotide (FMN) as the redox mediator. At the cathode, H+ ions were electroreduced to produce H2 gas. By introducing both ethanol biofuel and alcohol dehydrogenase to this photogalvanic cell, the cell current continued to flow, because NAD+ was converted to NADH by the biofuel and the enzyme. This cell provides not only electricity, but also H2 gas as by-products. This is an advantageous feature which common enzymatic fuel cells do not possess.

Keywords: adenine dinucleotide; biofuel; nicotinamide adenine; oxidation nicotinamide; dinucleotide hydrate; cell

Journal Title: Journal of Electronic Materials
Year Published: 2020

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