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Control of Carbon Content in Ultrafine Cemented Carbide by Heat Treatment in Reducing Atmospheres Containing Carbon Oxides

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In this work, the method of control of carbon content in the ultrafine-grained cemented carbide alloy was proposed. The treating of the WC-8Co-0.4VC-0.4Cr3C2 compacts was made in a CO + CO2 gas… Click to show full abstract

In this work, the method of control of carbon content in the ultrafine-grained cemented carbide alloy was proposed. The treating of the WC-8Co-0.4VC-0.4Cr3C2 compacts was made in a CO + CO2 gas mixture at CO concentrations from 0 to 80 vol.% during 50 min at the initial stage of the conventional sintering at a temperature of 700 °C. Conditions for increasing and decreasing the carbon content are CO concentrations of CO in gas mix more than 65 vol.% and less than 35 vol.%, respectively. It is shown that even a small deviation from the stoichiometric carbon content (0.3 wt.%) leads to an increase in porosity and a multiple decrease in the strength of the ultrafine-grained cemented carbide. A comparative analysis with literature data showed that the obtained ultrafine-grained solid alloy WC-8Co-0.4VC-0.4Cr3C2 with stoichiometric composition is not inferior in hardness and toughness to the analogs obtained by hot pressing and electrospark sintering.

Keywords: carbon; ultrafine; cemented carbide; control carbon; carbon content

Journal Title: Journal of Materials Engineering and Performance
Year Published: 2018

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