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Experimental Investigation of Phase Equilibria in the Fe-Cr-Si Ternary System

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Isothermal sections of the Fe-Cr-Si ternary system at 1000 and 1100 °C were studied using x-ray diffraction, scanning electron microscopy and electron probe micro-analysis. Isothermal sections were identified with seven and… Click to show full abstract

Isothermal sections of the Fe-Cr-Si ternary system at 1000 and 1100 °C were studied using x-ray diffraction, scanning electron microscopy and electron probe micro-analysis. Isothermal sections were identified with seven and six three-phase regions at 1000 and 1100 °C, respectively. The σ phase contains 6.2-20.2 at.% Si at 1000 °C and 8.3-21.2 at.% Si at 1100 °C. Fe and Cr can be entirely substituted by each other to form the continuous solid-solution ε or CrSi phases. The η phase is stable at 1100 °C because of the dissolution of Cr. Additionally, large solubility was detected in some binary compounds, e.g., up to 26.6 and 19.6 at.% Fe in αCr 5 Si 3 and Cr 3 Si at 1000 °C, respectively.

Keywords: phase; ternary system; phase equilibria; 1000 1100

Journal Title: Journal of Phase Equilibria and Diffusion
Year Published: 2020

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