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Analysis of collision-controlled time dependence of diffusion coefficient of polaron pairs from transient absorption spectra of conducting polymers

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We derived relations for time-dependent diffusion coefficient of photoexcited species determined from transient absorption spectra for various types of collision processes controlling decay of photoexcited species of conducting polymers. The… Click to show full abstract

We derived relations for time-dependent diffusion coefficient of photoexcited species determined from transient absorption spectra for various types of collision processes controlling decay of photoexcited species of conducting polymers. The method was applied for time-resolved experimental data of polaron pairs decay in 10-nm-thick thin films of regioregular poly(3-hexyl-thiophene).Graphical abstract

Keywords: conducting polymers; absorption spectra; diffusion coefficient; time; transient absorption; polaron pairs

Journal Title: Chemical Papers
Year Published: 2018

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