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Synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by ZnO

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An efficient method for the synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by nano-ZnO under solvent-free condition at room temperature was described. The method is… Click to show full abstract

An efficient method for the synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by nano-ZnO under solvent-free condition at room temperature was described. The method is compatible with a range of ethers including tricyclic ethers, tetracyclic ethers, pentacyclic ethers and hexacyclic ethers and have afforded the products with moderate to good yields. The ZnO could be reused up to three times and the product yield after three cycles is 87%.

Keywords: acyl chlorides; reaction ethers; chlorides catalyzed; synthesis chloroesters; ethers acyl; chloroesters reaction

Journal Title: Chemical Papers
Year Published: 2020

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