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Microfluidic synthesis of renewable biosorbent with highly comprehensive adsorption performance for copper (II)

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A microsphere biosorbent with uniform size (CV = 1.52%), controllable morphology and component, and high mechanical strength was synthesized from chitosan by microfluidic technology combining with chemical crosslinking and solvent… Click to show full abstract

A microsphere biosorbent with uniform size (CV = 1.52%), controllable morphology and component, and high mechanical strength was synthesized from chitosan by microfluidic technology combining with chemical crosslinking and solvent extraction. This chitosan microsphere (CS-MS) was prepared with a two-step solidification process, which was acquired by drying for the enhancement of mechanical property in final. The adsorption behavior of CS-MS towards copper (II) and main influencing factors on adsorption performance were investigated by batch experiments. Kinetic data hig-hlighted dominant chemical bonding along with electrons transferring in adsorption process. Isothermal analysis indicated that adsorption capacity was relevant to the number of active site. All these explorations provided a new direction for preparing highly comprehensive performance sorbent used in heavy metal treatment via microfluidic technology.

Keywords: adsorption; highly comprehensive; copper; performance; adsorption performance; microfluidic synthesis

Journal Title: Frontiers of Chemical Science and Engineering
Year Published: 2017

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