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Modified Rice Husk Silica from Biowaste: An Efficient Catalyst for Transesterification of Diethyl Malonate and Benzyl Alcohol

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Molybdenum and lanthanum oxide modified silica-based catalysts were prepared from the agricultural waste rice husk. These synthesized catalysts were characterized by various spectroscopic and non-spectroscopic techniques. The catalytic performance was… Click to show full abstract

Molybdenum and lanthanum oxide modified silica-based catalysts were prepared from the agricultural waste rice husk. These synthesized catalysts were characterized by various spectroscopic and non-spectroscopic techniques. The catalytic performance was investigated by transesterification reaction between diethyl malonate and benzyl alcohol in the liquid phase using modified silica as a heterogeneous catalyst. Molybdenum modified silica-based catalyst showed the highest conversion efficiency of 95.6% and selectivity of 96.8% for dibenzyl malonate. The reaction conditions were optimized to give maximum efficiency with the highest selectivity in a solvent-free green method.

Keywords: diethyl malonate; rice husk; malonate benzyl; silica; benzyl alcohol; catalyst

Journal Title: Waste and Biomass Valorization
Year Published: 2019

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