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Facile one-pot synthesis of novel dicyanoanilines fused to dithiane ring via a pseudo-four-component reaction

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Abstract1,3-Dithian-5-one 1 undergoes a convenient pseudo-four-component combination with different aldehydes 2 and two equivalents of malononitrile 3 in aqueous medium and in the presence of triethylamine. Novel dithian-fused dicyanoanilines 4… Click to show full abstract

Abstract1,3-Dithian-5-one 1 undergoes a convenient pseudo-four-component combination with different aldehydes 2 and two equivalents of malononitrile 3 in aqueous medium and in the presence of triethylamine. Novel dithian-fused dicyanoanilines 4 are formed efficiently in the mixture within 2–3 h. Products which are formed in high yields and precipitate spontaneously in the reaction mixtures have the potential for fluorescence activity.Graphical Abstract

Keywords: synthesis novel; four component; facile one; pot synthesis; one pot; pseudo four

Journal Title: Journal of the Iranian Chemical Society
Year Published: 2017

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