LAUSR

Adsorption is a process that utilizes porous solid materials to separate some solutes from gas or liquid mixtures. The extent of this separation is often determined using the adsorption isotherms, i.e., semi-empirical correlation for relating the amount of adsorbed substances by the solid medium to its associated concentration in fluid phase at constant temperature. Prior to employing an adsorption isotherm, its coefficients should be adjusted using experimental data of a considered adsorption system. In this study, the coefficients of Langmuir model have been predicted using various types of artificial neural networks (ANNs), support vector machines, and adaptive neuro fuzzy interface systems, and coupled scheme of ANN-genetic algorithm. The employed ANN types are multi-layer perceptron neural network (MLPNN), radial basis function neural network, cascade feedforward neural network, and generalized neural network. The considered coefficients tried to be modeled as functions of temperature, pH, adsorbent density, and adsorbate molecular weight. Predictive accuracies of the AI techniques have been compared utilizing different statistical indices such as correlation coefficient (R2), mean square error, and absolute average relative deviation (AARD%). The results indicated that MLPNN was the most accurate model for predicting the coefficients of Langmuir isotherm, due to its AARDs of 24.64 and 22.40% for the first and second coefficients, respectively.