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MCM-41 templating of semiconductors onto microwave-induced KOH-modified biomass-activated carbon for photo-mineralization of tetracycline: response surface methodology

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The quest for the availability of potable water in the sub-Sahara Africa is the trigger and impetus for this research work. Hence, this research work highlights the application of a… Click to show full abstract

The quest for the availability of potable water in the sub-Sahara Africa is the trigger and impetus for this research work. Hence, this research work highlights the application of a semiconductor photocatalyst (MCM-41 silica templating of Al2O3/ZnO/SnO2/TiO2 onto microwave-induced KOH-modified Pinus sylvestris cellulosic biomass-activated carbon) for photo-mineralization of tetracycline (TC) by the response surface methodology/central composite design approach/technique. This semiconductor photocatalyst’s surface microstructures were studied using Fourier transform-attenuated total reflectance, thermogravimetric analysis and Brunauer–Emmett–Teller/Barrett–Joyner–Halenda nitrogen sorptiometry–desorptiometry at cryogenic temperature (77 K). The results obtained from this microstructural analysis showed that the semiconductor photocatalyst was a thermally stable and multi-functional material that photo-degraded 99.25% of 20 mg/L of TC, with a half-life of 3.52 min and 9.93 mg of TC photo-degraded per g of semiconductor photocatalyst. This also showed that this semiconductor photocatalyst was efficient and, thus, a suitable and promising photocatalytic candidate for the degradation of other antibiotics other than TC in future perspective.

Keywords: onto microwave; methodology; surface; photo; semiconductor photocatalyst

Journal Title: International Journal of Environmental Science and Technology
Year Published: 2018

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