LAUSR

In this paper, the grain boundary diffusion process (GBDP) using a Dy70Cu30 (at.%) alloy as the diffusion source was performed in a commercial sintered Nd–Fe–B magnet, and the effect of heat treatment time on the microstructure and magnetic properties of the magnet was investigated in detail. For the processed magnets heat-treated at 860 °C, as heat treatment time increased, the coercivity and the depth of (Nd,Dy)2Fe14B core–shell structure increased first and then decreased. However, when the heat treatment time was more than 2 h, the diffusion path of Dy from the Dy-rich shell phase into the Nd2Fe14B grains was revealed, and a nearly homogeneous (Nd,Dy)2Fe14B phase was formed, which brought on the decrease in both the depth of visible core–shell structure and the coercivity of Nd–Fe–B magnet.