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On the basis of a series of control experiments and nuclear magnetic resonance analyses, it is discovered that Boc-protected amino acid ligand coordinated to Pd center is partly replaced by… Click to show full abstract
On the basis of a series of control experiments and nuclear magnetic resonance analyses, it is discovered that Boc-protected amino acid ligand coordinated to Pd center is partly replaced by N,N-dimethylformamide, and H2O can inhibit coordination of N,N-dimethylformamide to Pd center. The novel action mechanism perfectly explains H2O promotion for stereoselectivity in Pd(II)-catalyzed C―H arylation of diarylphosphinamides with arylboronic acids.
Keywords:
mechanism;
arylation diarylphosphinamides;
stereoselectivity catalyzed;
arylboronic acids;
catalyzed arylation;
diarylphosphinamides arylboronic
Journal Title: Chemical Research in Chinese Universities
Year Published: 2019
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Journal Title: Chemical Research in Chinese Universities
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!