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A desymmetrization approach for the synthesis of the A-B-C tricycle intermediate of iso-merrilactone A was described. The key steps of this synthesis to efficiently access the tetracyclic Illicium sesquiterpenes core… Click to show full abstract
A desymmetrization approach for the synthesis of the A-B-C tricycle intermediate of iso-merrilactone A was described. The key steps of this synthesis to efficiently access the tetracyclic Illicium sesquiterpenes core included an intramolecular aldol cyclization and an oxidative lactonization reaction. A novel Au catalyzed hydrolytic cyclorearrangement cascade reaction was explored in the initial stage.
Keywords:
iso merrilactone;
synthesis ring;
synthesis;
core
Journal Title: Chemical Research in Chinese Universities
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical Research in Chinese Universities
Year Published: 2019
Link to full text (if available)
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recommendations!