LAUSR

A magnetic ionic liquid (abridged as MIL) [C 6 mim] 5 [Dy(SCN) 8 ] was prepared and used as the magnetic lubricant of a steel-steel sliding pair. The tribological properties of the as-prepared MIL were evaluated with a commercially obtained magnetic fluid lubricant (abridged as MF; the mixture of dioctyl sebacate and Fe 3 O 4 , denoted as DIOS-Fe 3 O 4 ) as a control. The lubrication mechanisms of the two types of magnetic lubricants were discussed in relation to worn surface analyses by SEM-EDS, XPS, and profilometry, as well as measurement of the electric contact resistance of the rubbed steel surfaces. The results revealed that the MIL exhibits better friction-reducing and antiwear performances than the as-received MF under varying test temperatures and loads. This is because the MIL participates in tribochemical reactions during the sliding process, and forms a boundary lubrication film composed of Dy 2 O 3 , FeS, FeSO 4 , nitrogen-containing organics, and thioether on the rubbed disk surface, thereby reducing the friction and wear of the frictional pair. However, the MF is unable to form a lubricating film on the surface of the rubbed steel at 25 °C, though it can form a boundary film consisting of Fe 3 O 4 and a small amount of organics under high temperature. Furthermore, the excessive Fe 3 O 4 particulates that accumulate in the sliding zone may lead to enhanced abrasive wear of the sliding pair.