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Nb2O5 nanotubes on carbon cloth for high performance sodium-ion capacitors

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Hybrid sodiumion capacitors (SICs) bridge the gap between the supercapacitors (SCs) and batteries and have huge potential applications in large-scale energy storage. However, designing appropriate anode materials with fast kinetics… Click to show full abstract

Hybrid sodiumion capacitors (SICs) bridge the gap between the supercapacitors (SCs) and batteries and have huge potential applications in large-scale energy storage. However, designing appropriate anode materials with fast kinetics behavior as well as long cycle life to match with the cathode electrodes remains a crucial challenge. Herein, Nb2O5 nanotubes and nanowire-to-nanotube homo-junctions were directly grown on the carbon cloth (CC) via a simple hydrothermal process through regulating the pH value of solution. The as-prepared Nb2Os@CC nanotubes displayed a high reversible capacity of 175 mA h g at the current density of 1 A g with the coulombic efficiency of 97% after 1500 cycles. Besides, the SICs fabricated with Nb2Os@CC and activated carbon (AC) electrode materials showed a high energy density of 195 W h kg ' at 120 W kg”1, a power density of 7328 W kg ' at 28 W h kg and 80% of the capacitance retention after 5000 cycles. Additionally, the flexible SIC devices can operate normally at various bendable conditions. The Nb2Os@CC nanotubes in this work can be promising electrode materials in flexible and wearable energy storage devices.

Keywords: cloth high; carbon; nb2o5 nanotubes; carbon cloth; nanotubes carbon

Journal Title: Science China Materials
Year Published: 2020

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