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X-ray fluorescence analysis of Portland cement and clinker for major and trace elements: accuracy and precision

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Accurate, rapid methods for controlling and determining composition are necessary to aid in classification of cements and for correlation of performance characteristics with composition. X-ray fluorescence (XRF) is used to… Click to show full abstract

Accurate, rapid methods for controlling and determining composition are necessary to aid in classification of cements and for correlation of performance characteristics with composition. X-ray fluorescence (XRF) is used to adjust the raw material proportions and to control the process conditions. The aim of the present study was to establish a reliable analytical program by X-ray fluorescence spectrometry, based on the choice of a well-defined range of standards, which are used to control the quality of the clinker. The results showed a second order polynomial regression model that could properly interpret the experimental data with an R2 value >0.97 even after correction for some elements. The results obtained indicate the reliability, reproducibility, and the ease of use of the established program.

Keywords: analysis portland; fluorescence analysis; clinker; ray fluorescence; ray

Journal Title: Journal of the Australian Ceramic Society
Year Published: 2017

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