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Outstanding visible photocatalytic activity of a new mixed bismuth titanatate material

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Abstract In this work, a new photocatalyst based on bismuth titanates with outstanding visible photocatalytic activity was prepared by a facile hydrothermal method. The synthesised material showed visible activity as… Click to show full abstract

Abstract In this work, a new photocatalyst based on bismuth titanates with outstanding visible photocatalytic activity was prepared by a facile hydrothermal method. The synthesised material showed visible activity as high as UV activity of commercial TiO 2 P25 under the same experimental conditions for phenol degradation. A wide characterisation of the photocatalyst was performed. The material was composed of three phases; majority of Bi 20 TiO 32 closely interconnected to Bi 4 Ti 3 O 12 and amorphous TiO 2 . The high visible activity showed by this material could be ascribed to a combination of several features; i.e. low band gap energy value (2.1 eV), a structure allowing a good separation path for visible photogenerated electron-holes pairs and a relatively high surface area. This photocatalyst appeared as a promising material for solar and visible applications of photocatalysis.

Keywords: photocatalytic activity; outstanding visible; visible photocatalytic; material; bismuth; activity

Journal Title: Applied Surface Science
Year Published: 2017

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