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Self-assembled monolayer of mica coating using organobisphosphonic acid

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Abstract A hexadecane-1,1-bisphosphonic acid monolayer was grafted on the surface of muscovite mica via a simple self-assembled method. The result of AFM showed that the height of the bisphosphonate SAMs… Click to show full abstract

Abstract A hexadecane-1,1-bisphosphonic acid monolayer was grafted on the surface of muscovite mica via a simple self-assembled method. The result of AFM showed that the height of the bisphosphonate SAMs was about 2.40 nm, corresponding to both monolayer-like coverage and the hydrocarbon chain length. TOF-SIMS indicated that the reaction between bisphosphonic acid and silicon was took place on the surface of mica substrate. It can be proved from IR, AFM, XPS, and TOF-SIMS that the alkylbisphosphonate SAM was bonded to the mica with the mode of double-tridentate attachment. In addition, organobisphosphonate SAM possessed excellent orderliness and stability, which provides a theoretical basis for its efficient application in the field of organic modification.

Keywords: mica; acid; assembled monolayer; self assembled

Journal Title: Applied Surface Science
Year Published: 2018

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