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The effect of refractory (Zr, Hf) elements on the magnetocaloric property of Mn-based alloys

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Abstract This study was investigated the effect of additional elements on the magnetocaloric property in MnFeMPGe (M = Zr, Hf) alloys. The magnetocaloric property of alloys depending on the decrease of the… Click to show full abstract

Abstract This study was investigated the effect of additional elements on the magnetocaloric property in MnFeMPGe (M = Zr, Hf) alloys. The magnetocaloric property of alloys depending on the decrease of the additional element was enhanced about 7.52J/kgK and 94.84J/kg at 242 K in the Mn1.2Fe0.79Zr0.01P0.6Ge0.4 alloy. We were able to deduce that the magnetocaloric property was affected by the strong magneto-crystalline anisotropy resulting from high volume % of main phase (≥50%). The strong magneto-crystalline anisotropy was induced by the homogeneous dendritic structures and distinct main peak with 11 2 ¯ 0 plane in Mn1.2Fe0.8−x(Zr,Hf)xP0.6Ge0.4 (x = 0.01, 0.05, 0.1) alloys.

Keywords: refractory elements; property; elements magnetocaloric; effect refractory; magnetocaloric property

Journal Title: Applied Surface Science
Year Published: 2019

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