LAUSR

Abstract Hierarchically branched multi-metallic nanoassembles are promising catalysts extensively used in catalytic fields because of their unique structural features and multicompositions advantages. Herein, three-dimensional (3D) hierarchical zigzag-branched urchin-like PdCuPt superstructures (HZBUS) were prepared by a one-pot wet-chemical method, where polyethylene oxide (PEO) and KBr served as directing agents. The specific architectures provided abundant active sites highly available for reactants, in turn showing highly enlarged electrochemically active surface area (16.79 m2 g−1Pd). The as-obtained PdCuPt HZBUS displayed dramatically enhanced catalytic activity and improved long-term durability for formic acid oxidation reaction (FAOR), surpassing homemade PdCu nanoparticles (NPs), commercial Pd black and Pt/C catalysts. This work offers a new strategy for construction of advanced multimetallic electrocatalysts with charming superstructures and high-efficient performances in fuel cells.