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Construction of full spectrum-driven CsxWO3/g-C3N4 heterojunction catalyst for efficient photocatalytic CO2 reduction

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Abstract Full spectrum-driven CsxWO3/g-C3N4 catalyst was successfully synthesized by the combination of solvothermal and ultrasonication methods and used in CO2 photocatalytic reduction. The experimental results suggested that 20 wt% CsxWO3/g-C3N4 catalyst… Click to show full abstract

Abstract Full spectrum-driven CsxWO3/g-C3N4 catalyst was successfully synthesized by the combination of solvothermal and ultrasonication methods and used in CO2 photocatalytic reduction. The experimental results suggested that 20 wt% CsxWO3/g-C3N4 catalyst possessed the best yield of CH4 under NIR and full spectrum light irradiation, which were 1.72 and 6.79 μmol·g−1·h−1, respectively. This outstanding photocatalytic activity could be attributed to the localized surface plasmonic resonance effect and the formation of heterojunction structure, which led to the improved charge separation efficiency, good light-harvesting ability and broadened light response.

Keywords: spectrum driven; catalyst; full spectrum; csxwo3 c3n4

Journal Title: Applied Surface Science
Year Published: 2021

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