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Melamine trisulfonic acid catalyzed regioselective nitration of aromatic compounds with sodium nitrate under solvent-free conditions

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Abstract A simple and efficient method for the regioselective nitration of various aromatic compounds by using sodium nitrate in the presence of melamine trisulfonic acid, is reported. This method provides… Click to show full abstract

Abstract A simple and efficient method for the regioselective nitration of various aromatic compounds by using sodium nitrate in the presence of melamine trisulfonic acid, is reported. This method provides several advantages such as good selectivity between ortho and para positions of aromatic compounds, simple work-up, short reaction times and high yields of the products.

Keywords: regioselective nitration; aromatic compounds; trisulfonic acid; melamine trisulfonic; sodium nitrate

Journal Title: Arabian Journal of Chemistry
Year Published: 2017

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